Symmetry And Topology In Chemical Reactivity is popular PDF and ePub book, written by Pieter E Schipper in 1994-04-22, it is a fantastic choice for those who relish reading online the Science genre. Let's immerse ourselves in this engaging Science book by exploring the summary and details provided below. Remember, Symmetry And Topology In Chemical Reactivity can be Read Online from any device for your convenience.
Symmetry And Topology In Chemical Reactivity Book PDF Summary
This well-illustrated book develops, using only the ideas of basic quantum chemistry (e.g. perturbation and symmetry theory), a fundamental conceptual and theoretical framework for chemical reactivity. By feeding the role of symmetry and chemical group topology directly into the development, the analysis generates and explains the successful features of simpler reactivity theories (e.g. frontier orbital theory, the isolobal concept, PMO theory, the Woodward-Hoffmann rules), as well as defines their limitations. The unifying construct is that of a group-resolved correlation diagram, which is shown to represent the formal quantization of the electron arrow, replacing the concept of classical point electrons moving between groups with the concept of quantum electron matter waves which evolve with the evolving nuclear and chemical group structure. The use of the concept of chemical groups (functional group system, substituents, solvents) is central to the development, localising the evolutionary electrons within the functional groups and leading to an isolation and analytic definition of substituent and solvent (catalytic) effects as explicit functions of the reaction coordinate. Each archetypical reaction family is represented by fully-worked examples: viz. aliphatic nucleophilic substitution, aromatic electrophilic substitution, inorganic rearrangements, electrocyclic additions, Diels-Alder additions and addition stages in chiral reactions.
Detail Book of Symmetry And Topology In Chemical Reactivity PDF
- Author : Pieter E Schipper
- Release : 22 April 1994
- Publisher : World Scientific
- ISBN : 9789814502696
- Genre : Science
- Total Page : 286 pages
- Language : English
- PDF File Size : 18,9 Mb
If you're still pondering over how to secure a PDF or EPUB version of the book Symmetry And Topology In Chemical Reactivity by Pieter E Schipper, don't worry! All you have to do is click the 'Get Book' buttons below to kick off your Download or Read Online journey. Just a friendly reminder: we don't upload or host the files ourselves.