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Study of lithium deposition and applicability of solid polymer electrolytes in lithium cells Band 10 Book PDF Summary

Lithium (Li) deposition is a problem in Li batteries (LB) – both Li metal (LMB) and Li-ion (LIB) batteries – which limits their performance in terms of power and energy density. Two trends can be identified in the advancement of LBs concerning the problem of Li deposition: optimization of the existing system (the state-of-the-art LIBs) and further development of cell components such as electrolytes. This work addresses both approaches. In the first part, this study investigates Li deposition in LMB and LIBs. A novel method to study the Li-based transport mechanisms in LIBs is introduced. Later the kinetic deviations between anode and cathode as a consequence of aging and the relation of these deviations to the occurrence of Li-plating are discussed. In the second part, the applicability of PEO-based solid polymer electrolytes for LMBs to overcome the Li plating issue is investigated. The introduction of various interfacial interlayers at the cathode/electrolyte interphase was studied to improve the electrochemical stability of the cells. Cells with an in-situ electro-deposited interlayer showed the best cyclability.

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Study of lithium deposition and applicability of solid polymer electrolytes in lithium cells  Band 10
  • Author : Sanaz Momeni Boroujeni
  • Release : 30 December 2022
  • Publisher : Cuvillier Verlag
  • ISBN : 9783736967090
  • Genre : Technology & Engineering
  • Total Page : 176 pages
  • Language : English
  • PDF File Size : 7,5 Mb

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