Polyoxometalate Chemistry Some Recent Trends is popular PDF and ePub book, written by Francis Secheresse in 2013-06-11, it is a fantastic choice for those who relish reading online the Science genre. Let's immerse ourselves in this engaging Science book by exploring the summary and details provided below. Remember, Polyoxometalate Chemistry Some Recent Trends can be Read Online from any device for your convenience.
Polyoxometalate Chemistry Some Recent Trends Book PDF Summary
The book highlights recent prominent results in the domain of the synthesis of new polyoxometalates with a specific attention to polyoxothioanions, and provides some novelties and perspectives in selected domains such as magnetism, luminescence and nanochemistry, and macroions self-assembly in solutions. The case of “one-pot” syntheses often used and reported in POMs synthesis is studied in terms of more complex solution speciation processes related to highly dynamical situation connected to factors such as pH, ionic strength, reaction time, temperature, counterion nature, concentration of starting materials, presence of electron donors and redox potentials. The behavior of macroions (2nm-6nm size range) in solution is shown to be quite different from the simple ionic solution or colloidal systems (Debye-Huckel model). Their self-assembling into a single-layered, spherical, hollow vesicle structure, namely the “blackberry” structure, is clearly described. Examples of spin clusters with tunable interactions are given and single molecule magnets based on POMs are specifically tackled. Besides paramagnetic transition metal centres and lanthanoid ions encapsulated in archetypal lacunary polyoxoanions, magnetically functionalized Kleperates are described, their discovery tracing back nearly 15 years.
Detail Book of Polyoxometalate Chemistry Some Recent Trends PDF
- Author : Francis Secheresse
- Release : 11 June 2013
- Publisher : World Scientific
- ISBN : 9789814458993
- Genre : Science
- Total Page : 360 pages
- Language : English
- PDF File Size : 8,7 Mb
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