Organocatalytic Dynamic Kinetic Resolution is popular PDF and ePub book, written by Hélène Pellissier in 2022-05-06, it is a fantastic choice for those who relish reading online the Science genre. Let's immerse ourselves in this engaging Science book by exploring the summary and details provided below. Remember, Organocatalytic Dynamic Kinetic Resolution can be Read Online from any device for your convenience.
Organocatalytic Dynamic Kinetic Resolution Book PDF Summary
In a classical kinetic resolution, two enantiomers of a racemate are transformed into chiral products at different rates with a maximum theoretical yield of 50%. However, the need to reduce costs and waste in synthesis have led to efforts to develop novel resolution procedures proceeding beyond this 50% limited yield. This has led to the evolution of classical kinetic resolution into dynamic kinetic resolution (DKR), allowing a quantitative yield of one of the enantiomers. DKR combines the resolution step of kinetic resolution with an in-situ racemization of the chirally-labile substrate. It is only in the last two decades that chiral green organocatalysts have been demonstrated to be capable of promoting DKRs considerably expanding the synthetic scope of the powerful concept of DKR. Collecting all the developments in the field of DKR, this book shows that a wide variety of organocatalysts allow excellent levels of stereocontrol and yields in many types of transformations. It is a great resource for academics and industrialists interested in green enantioselective catalytic reactions.
Detail Book of Organocatalytic Dynamic Kinetic Resolution PDF
- Author : Hélène Pellissier
- Release : 06 May 2022
- Publisher : Royal Society of Chemistry
- ISBN : 9781839166365
- Genre : Science
- Total Page : 171 pages
- Language : English
- PDF File Size : 11,9 Mb
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