Material Designs and New Physical Properties in MX and MMX Chain Compounds is popular PDF and ePub book, written by Masahiro Yamashita in 2012-12-13, it is a fantastic choice for those who relish reading online the Science genre. Let's immerse ourselves in this engaging Science book by exploring the summary and details provided below. Remember, Material Designs and New Physical Properties in MX and MMX Chain Compounds can be Read Online from any device for your convenience.
Material Designs and New Physical Properties in MX and MMX Chain Compounds Book PDF Summary
This is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.
Detail Book of Material Designs and New Physical Properties in MX and MMX Chain Compounds PDF
- Author : Masahiro Yamashita
- Release : 13 December 2012
- Publisher : Springer Science & Business Media
- ISBN : 9783709113172
- Genre : Science
- Total Page : 275 pages
- Language : English
- PDF File Size : 13,8 Mb
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