A Novel Heme Thiolate Peroxygenase AaeAPO and Its Implications for C H Activation Chemistry is popular PDF and ePub book, written by Xiaoshi Wang in 2015-10-16, it is a fantastic choice for those who relish reading online the Science genre. Let's immerse ourselves in this engaging Science book by exploring the summary and details provided below. Remember, A Novel Heme Thiolate Peroxygenase AaeAPO and Its Implications for C H Activation Chemistry can be Read Online from any device for your convenience.
A Novel Heme Thiolate Peroxygenase AaeAPO and Its Implications for C H Activation Chemistry Book PDF Summary
In this thesis, Xiaoshi Wang investigates the function and mechanism of a newly discovered heme-thiolate peroxygenase, AaeAPO. This enzyme class comes from Agrocybe aegerita and is used in the conversion of inert hydrocarbons to alcohols. Xiaoshi's work focuses on an extracellular P450 enzyme which is not limited in its stability and lack of solubility and therefore is relevant for widespread industrial use. The author demonstrates that the peroxygenase catalyzes a wide range of reactions. In some cases the author even describes very difficult transformations in molecules that are highly inert. Her detailed investigations provide a mechanistic framework for how the peroxygenase catalyzes such a large number of reactions. A major highlight of this thesis is the identification of key short-lived intermediates in the catalytic cycle of the peroxygenase, using rapid kinetic and spectroscopic methods, as well as the elucidation of the thermodynamic properties of these high-energy intermediates. This work adds new insight into an important class of enzymes.
Detail Book of A Novel Heme Thiolate Peroxygenase AaeAPO and Its Implications for C H Activation Chemistry PDF
- Author : Xiaoshi Wang
- Release : 16 October 2015
- Publisher : Springer
- ISBN : 9783319032368
- Genre : Science
- Total Page : 153 pages
- Language : English
- PDF File Size : 14,6 Mb
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