Functionalised N Heterocyclic Carbene Complexes is popular PDF and ePub book, written by Olaf Kühl in 2010-02-02, it is a fantastic choice for those who relish reading online the Science genre. Let's immerse ourselves in this engaging Science book by exploring the summary and details provided below. Remember, Functionalised N Heterocyclic Carbene Complexes can be Read Online from any device for your convenience.
Functionalised N Heterocyclic Carbene Complexes Book PDF Summary
N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can anchor free carbenes to the metal site, introduce hemilability, provide a means to immobilise transition metal carbene catalysts, introduce chirality, provide a chelate ligand or bridge two metal centres. NHC can be attached to carbohydrates and campher, derived from amino acids and purines, they can be used as organocatalysts mimicking vitamin B1 or as weak “solvent” donors in lanthanide chemistry. Functionalised N-Heterocyclic Carbene Complexes describes major trends in functionalised NHC ligands, aiming to assist readers in their attempts to develop and apply their own functionalised carbenes. After an introduction to the chemistry and behaviour of NHC, the book gives a detailed description of functionalised carbenes and their complexes according to a range of functional groups, each with a discussion of the synthetic route, structure, stability and performance. Functionalised N-Heterocyclic Carbene Complexes is an essential guide to fine-tuning this important class of compounds for practitioners, researchers and advanced students working in synthetic organometallic and organic chemistry and catalysis.
Detail Book of Functionalised N Heterocyclic Carbene Complexes PDF
- Author : Olaf Kühl
- Release : 02 February 2010
- Publisher : John Wiley & Sons
- ISBN : 9780470685846
- Genre : Science
- Total Page : 364 pages
- Language : English
- PDF File Size : 14,8 Mb
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